Fungicidal active ingredients combinations

ABSTRACT

The novel active compound combinations of methoximinoacetamide derivatives of the general formula (I),  
                 
 
     in which  
     R 1  represents unsubstituted or fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i- or t-butyl-, inethoxy-, ethoxy- or phenoxy-substituted phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl, indanyl, 2-benzofuranyl, 2-benzothienyl, 2-thienyl or 2-furanyl,  
     and the active compound groups (1) to (58) listed in the description have very good fungicidal properties.

[0001] The present relation relates to novel active compoundcombinations which consist of known methoximinoacetamide derivatives andfurther known fungicidally active compounds, and which are highlysuitable for controlling phytopathogenenic fungi.

[0002] It is already known that alkoximinoacetamide derivatives havefungicidal properteis (cf. WO 96/23763). The activity of these compoundsis good; however, at low application rates it is in some cases notsatisfactory.

[0003] Furthermore, it is already known that a large number of triazolederivatives, aniline derivatives, dicarboximides and other heterocyclescan be employed for controlling fungi (cf. EP-A 0 040 345, DE-A 22 01063, DE-A 23 24 010, Pesticide Manual, 9th. Edition (1991), pages 249and 827, EP-A 0 382 375 and EP-A 0 515 901). Likewise, the activity ofthese compounds is not always satisfactory at low application rates.

[0004] Finally, it is also known that1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazo-lidinimine can beused for controlling animal pests such as insects (cf. Pesticide Manual,9th. Edition (1991), page 491). However, fungicidal properties havehitherto not been described for this compound.

[0005] Furthermore, it is already known that1-(3,5-dimethyl-isoxazole-4-sulphonyl)-2-chloro-6,6-difluoro-[1,3]-dioxolo-[4,5f]-benzimidazolehas fungicidal properties (cf. WO 97-06171).

[0006] Furthermore, it is already known that substitutedazadioxacycloalkenes have fungicidal properties (cf. EP-B-712 396).

[0007] Finally, it is also known that substituted halogenopyrimidineshave fungicidal properties (cf. DE-AI-196 46 407, EP-B-712 396).

[0008] It has now been found that the novel active compound combinationscomprising methoximinoacetamide derivatives of the general formula (I),

[0009] in which

[0010] R¹ represents unsubstituted or fluorine-, chlorine-, bromine-,methyl-, ethyl-, n- or i-propyl-, n-, i- or t-butyl-, methoxy-, ethoxy-or phenoxy-substituted phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl,indanyl, 2-benzofuranyl, 2-benzothienyl, 2-thienyl or 2-furanyl, and

[0011] (1) a triazole derivative of the formula

[0012] in which

[0013] X represents chlorine or phenyl and

[0014] Y represents

[0015] and/or

[0016] (2) the triazole derivative of the formula

[0017] and/or

[0018] (3) an aniline derivative of the formula

[0019] in which

[0020] R¹ represents hydrogen or methyl,

[0021] and/or

[0022] (4)N-[1-(4-chloro-phenyl)-ethyl]-2,2-dichloro-1-ethyl-3-methyl-cyclopropane-carboxamideof the formula

[0023]  and/or

[0024] (5) the zinc propylene-1,2-bis-(dithiocarbamidate) of the formula

[0025] and/or

[0026] (6) at least one thiocarbamate of the formula

[0027] Me=Zn or Mn or a mixture of Zn and Mn

[0028] and/or

[0029] (7) the aniline derivative of the formula

[0030] and/or

[0031] (8) the compound of the formula

[0032] and/or

[0033] (9) the benzothiadiazole derivative of the formula

[0034] and/or

[0035] (10) the8-t-butyl-2-(N-ethyl-N-n-propyl-amino)-methyl-1,4-dioxaspiro[5,4]-decaneof the formula

[0036] and/or

[0037] (11) the compound of the formula

[0038] and/or

[0039] (12) the compound of the formula

[0040] and/or

[0041] (13) the compound of the formula

[0042] and/or

[0043] (14) the cyanoxime derivative of the formula

[0044] and/or

[0045] (15) a pyrimidine derivative of the formula

[0046] in which

[0047] R² represents methyl or cyclopropyl,

[0048] and/or

[0049] (16) an aniline derivative of the formula

[0050] and/or

[0051] (17) the morpholine derivative of the formula

[0052] and/or

[0053] (18) the phthalimide derivative of the formula

[0054] and/or

[0055] (19) the phosphorus compound of the formula

[0056] and/or

[0057] (20) the hydroxyethyl-triazole derivative of the formula

[0058] and/or

[0059] (21) the1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimine of theformula

[0060] and/or

[0061] (22) the oxazolidinedione of the formula

[0062] and/or

[0063] (23) the benzamide derivative of the formula

[0064] and/or

[0065] (24) a guanidine derivative of the formula

[0066] in which

[0067] m represents integers from 0 to 5 and

[0068] R³ represents hydrogen (17 to 23%) or the radical of the formula

[0069] and/or

[0070] (25) the triazole derivative of the formula

[0071] and/or

[0072] (26) the halogeno-benzimidazole of the formula

[0073] and/or

[0074] (27) the halogenopyrimidine of the formula

[0075] and/or

[0076] (28) the tetrachloro-isophthalo-dinitrile of the formula

[0077] and/or

[0078] (29) the compound of the formula

[0079] and/or

[0080] (30) the pyridinamine of the formula

[0081] and/or

[0082] (31) the thiazolecarboxamide of the formula

[0083] and/or

[0084] (32) the sulphonamide of the formula

[0085] and/or

[0086] (33) the compound of the formula

[0087] and/or

[0088] (34) the compound of the formula

[0089] and/or

[0090] (35) the compound of the formula

[0091] and/or

[0092] (36) the diamide of the formula

[0093] and/or

[0094] (37) the methoxyacrylate derivative of the formula

[0095] and/or

[0096] (38) the quinoline derivative of the formula

[0097] and/or

[0098] (39) the phenylamide derivative of the formula

[0099] and/or

[0100] (40) the phenylamide derivative of the formula

[0101] and/or

[0102] (41) the dicarboxime derivative of the formula

[0103] and/or

[0104] (42) the phosphonic acid of the formula

[0105] and/or

[0106] (43) the pyrrole derivative of the formula

[0107] and/or

[0108] (44) the phenyl carbonate of the formula

[0109] and/or

[0110] (45)

a) copper oxychloride  (XXXXVIa)

b) copper hydroxide  (XXXXVIb)

[0111] and/or

[0112] (46) the imidazole derivative of the formula

[0113] and/or

[0114] (47) a triazole derivative of the formula

[0115] (48) the compound of the formula

[0116] and/or

[0117] (49)N-methyl-2-(methoxyimino)-2-[2-([1-(3-tri-fluoro-methyl-phenyl)ethoxy]iminomethyl)phenyl]acetamideof the formula

[0118] and/or

[0119] (50)2-[2-([2-phenyl-2-methoxyimino-1-methylethyl]-imino-oxymethyl)phenyl]-2-methoxyimino-N-methylacetamideof the formula

[0120] and/or

[0121] (51)2-[2-([2-(4-fluorophenyl)-2-methoxyimino-1-methylethyl]-iminooxymethyl)phenyl]-2-methoxyimino-N-methyl-acetamideof the formula

[0122] and/or

[0123] (52)2-[4-methoxy-3-(1-methylethoxy)-1,4-diazabuta-1,3-dienyl-oxymethyl]phenyl-2-methoximino-N-methyl-acetamideof the formula

[0124] and/or

[0125] (53) methylN-(2-[1-(4-chlorophenyl)pyrazol-3-yloxymethyl]phenyl)-N-methoxycarbamateof the formula

[0126] and/or

[0127] (54)2,4-dihydro-5-methoxy-2-methyl-4-[2-([([1-(3-tri-fluoromethyl-phenyl)ethylidene]amino)oxy]methyl)phenyl]-3H-1,2,4-triazol-3-oneof the formula

[0128] and/or

[0129] (55) the compound of the formula

[0130] and/or

[0131] (56) the compound of the formula

[0132] and/or

[0133] (57) a compound of the formula

[0134] in which

[0135] R¹ represents fluorine (XXXXXVIIIa) or chlorine (XXXXXVIIIb),

[0136] and/or

[0137] (58) a compound of the formula

[0138] have very good fungicidal properties.

[0139] Surprisingly, the fungicidal activity of the active compoundcombinations according to the invention is considerably higher than thesum of the activities of the individual active compounds. Thus, anunforeseeable, true synergistic effect is present, and not just anaddition of activities.

[0140] From the structural formula of the active compound of the formula(I), it can be seen that the compound can be present as E or Z isomers.Accordingly, the product can be present as a mixture of differentisomers or else in the form of a single isomer. Preference is given tocompounds of the formula (I) in which the compounds of the formula (I)are present as E isomer.

[0141] Preference is given to compounds of the formula (I), in which R¹represents unsubstituted or fluorine-, chlorine-, bromine-, methyl- orethyl-substituted phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl,indanyl, 2-thienyl or 2-furanyl.

[0142] Particular preference is given to compounds of the formula (I) inwhich R¹ represents unsubstituted or fluorine-, chlorine-, bromine-,methyl- or ethyl-substituted phenyl, 2-naphthyl,1,2,3,4-tetrahydronaphthyl or indanyl.

[0143] Specifically, mention may be made of the compounds of the formula(Ia)

[0144] of the formula (Ib)

[0145] of the formula (Ic)

[0146] of the formula (Id)

[0147] of the formula (Ie)

[0148] and of the formula (If)

[0149] and their isomers, as described above.

[0150] The formula (II) includes the compounds

[0151]1-(4-chloro-phenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-one ofthe formula

[0152]1-(4-chloro-phenoxy)-3,3-dimethyl-1-(,2,4-triazol-1-yl)-butan-2-ol ofthe formula

[0153] and

[0154]1-(4-phenyl-phenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-ol ofthe formula

[0155] The formula (IV) includes the aniline derivatives of the formulae

[0156] It is evident from the structural formula for the active compoundof the formula (V) that the compound has three asymmetricallysubstituted carbon atoms. The product may therefore be present as amixture of different isomers, or else in the form of a single component.Particular preference is given to the compounds

[0157]N-(R)-[1-(4-chloro-phenyl)-ethyl]-(1S)-2,2-dichloro-1-ethyl-3t-methyl-1R-cyclopro-panecarboxamideof the formula

[0158] and

[0159]N-(R)-[1-(4-chloro-phenyl)-ethyl]-(1R)-2,2-dichloro-1-ethyl-3t-methyl-1R-cyclopro-panecarboxamideof the formula

[0160] The formula (VII) includes the compounds

[0161] (VIIa) Me=Zn (zineb),

[0162] (VIIb) Me=Mn (maneb) and

[0163] (VIIc) mixture of (VIIa) and (VIIb) (mancozeb).

[0164] The formula (XVI) includes the compounds

[0165] (XVIa) R²═CH₃ (pyrimethanil) and

[0166] The hydroxyethyl-triazole derivative of the formula (XXI) can bepresent in the “thiono” form of the formula

[0167] or in the tautomeric “mercapto” form of the formula

[0168] For simplicity's sake, only the “thiono” form is given in eachcase.

[0169] The guanidine derivative of the formula (XXV) is a substancemixture with the common name guazatine.

[0170] The components which are present in the active combinationsaccording to the invention are also known. Specifically, the activecompounds are described in the following publications:

[0171] (1) compounds of the formula (II)

[0172] DE-A 22 01 063

[0173] DE-A 23 24 010

[0174] (2) compound of the formula (III)

[0175] EP-A 0 040 345

[0176] (3) compounds of the formula (IV)

[0177] Pesticide Manual, 9th Ed. (1991), pages 249 and 827

[0178] (4) compound of the formula (V) and individual derivativesthereof

[0179] EP-A 0 341 475

[0180] (5) compound of the formula (VI)

[0181] Pesticide Manual, 9th Ed. (1991), page 726

[0182] (6) compounds of the formula (VII)

[0183] Pesticide Manual, 9th Ed. (1991), pages 529, 531 and 866

[0184] (7) compound of the formula (VW)

[0185] EP-A 0 339 418

[0186] (8) compound of the formula (IX)

[0187] EP-A 0 472 996

[0188] (9) compound of the formula (X)

[0189] EP-A 0 313 512

[0190] (10) compound of the formula (XI)

[0191] EP-A 0 281 842

[0192] (11) compound of the formula (XII)

[0193] EP-A 0 382 375

[0194] (12) compound of the formula (XIII)

[0195] EP-A-460 575

[0196] (13) compound of the formula (XIV)

[0197] DE-A 196 02 095

[0198] (14) compound of the formula (XV)

[0199] Pesticide Manual, 9th Ed. (1991), page 206

[0200] (15) compounds of the formula (XVI)

[0201] EP-A 0 270 111

[0202] EP-A 0 310 550

[0203] (16) compound of the formula (XVII)

[0204] Pesticide Manual, 9th Ed. (1991), page 554

[0205] (17) compound of the formula (XVIII)

[0206] EP-A0219756

[0207] (18) compound of the formula (XIX)

[0208] Pesticide Manual, 9th Ed. (1991), page 431

[0209] (19) compound of the formula (XX)

[0210] Pesticide Manual, 9th Ed. (1991), page 443

[0211] (20) compound of the formula (XXI)

[0212] WO 96-16048

[0213] (21) compound of the formula (XXII)

[0214] Pesticide Manual, 9th Ed. (1991), page 491

[0215] (22) compound of the formula (XXIII)

[0216] EP-A 0 393 911

[0217] (23) compound of the formula (XXIV)

[0218] EP-A 0 600 629

[0219] (24) substance of the formula (XXV)

[0220] Pesticide Manual, 9th Ed. (1991), page 461

[0221] (25) compound of the formula (XXVI)

[0222] Pesticide Manual, 9th Ed. (1991), page 654

[0223] (26) compound of the formula (XXVII)

[0224] WO 97-06171

[0225] (27) compound of the formula (XXVIII)

[0226] DE-A1-196 46 407, EP-B-0 712 396

[0227] (28) compound of the formula (XXIX)

[0228] U.S. Pat. No. 3,290,353

[0229] (29) compound of the formula (XXX)

[0230] DE-A-156 7169

[0231] (30) compound of the formula (XXXI)

[0232] EP-A-0 031 257

[0233] (31) compound of the formula (XXXII)

[0234] EP-A-0 639 547

[0235] (32) compound of the formula (XXXIII)

[0236] EP-A-0 298 196

[0237] (33) compound of the formula (XXXIV)

[0238] EP-A-0 629 616

[0239] (34) compound of the formula (XXXV)

[0240] DE-A-2 149 923

[0241] (35) compound of the formula (XXXVI)

[0242] DE-A-2 012 656

[0243] (36) compound of the formula (XXXVII)

[0244] U.S. Pat. No. 1,972,961

[0245] (37) compound of the formula (XXXVIII)

[0246] EP-A-326 330

[0247] (38) compound of the formula (XXXIX)

[0248] EP-A 278 595

[0249] (39) compound of the formula (XXXX)

[0250] DE-A-3 030 026

[0251] (40) compound of the formula (XXXXI)

[0252] DE-A-2 903 612

[0253] (41) compound of the formula (XXXXII)

[0254] U.S. Pat. No. 2,553,770

[0255] (42) compound of the formula (XXXXIII)

[0256] known and commercially available

[0257] (43) compound of the formula (XXXXIV)

[0258] EP-A-206 999

[0259] (44) compound of the formula (XXXXV)

[0260] EP-A-78 663

[0261] (45) compounds of the formulae (XXXXVIa) and (XXXXVIb)

[0262] known and commercially available

[0263] (46) compound of the formula (XXXXVII)

[0264] DE-A-2 429 523

[0265] (47)

[0266] a) compound of the formula (XXXXVIIIa)

[0267] EP-A-112 284

[0268] b) compound of the formula (XXXXVIIIb)

[0269] DE-A-3 042 303

[0270] c) compound of the formula (XXXXVIIIc)

[0271] DE-A-3 406 993

[0272] d) compound of the formula (XXXXVIIId)

[0273] EP-A-68 813

[0274] e) compound of the formula (XXXXVIIIe)

[0275] DE-A-2551560

[0276] f) compound of the formula (XXXXVIIIf)

[0277] EP-A-145 294

[0278] g) compound of the formula (XXXXVIIIg)

[0279] DE-A-3 721 786

[0280] h) compound of the formula (XXXXVIIIh)

[0281] EP-A-234 242

[0282] i) compound of the formula (XXXXVIIIi)

[0283] EP-A-196 038

[0284] (48) compound of the formula (XXXXIX)

[0285] EP-A-253 213

[0286] (49) compound of the formula (XXXXX)

[0287] EP-A-596 254

[0288] (50) compound of the formula (XXXXXI)

[0289] WO 95/21154

[0290] (51) compound of the formula (XXXXXII)

[0291] WO 95/21154

[0292] (52) compound of the formula (XXXXXIII)

[0293] DE-A-195 28 651

[0294] (53) compound of the formula (XXXXXIV)

[0295] DE-A-44 23 612

[0296] (54) compound of the formula (XXXXXV)

[0297] WO 98/23155

[0298] (55) compound of the formula (XXXXXVI)

[0299] WO 97/15552

[0300] (56) compound of the formula (XXXXXVII)

[0301] EP-A-569 384

[0302] (57) compounds of the formula (XXXXXVIII)

[0303] EP-A-545 099

[0304] (58) compound of the formula (XXXXXVIX)

[0305] EP-A-600 629.

[0306] In addition to an active compound of the formula (1), the activecompound combinations according to the invention comprise at least oneactive compound of the compounds of groups (1) to (58). Additionally,they may comprise further fungicidally active additives.

[0307] The synergistic effect is particularly pronounced when the activecompounds in the active compound combinations according to the inventionare present in certain weight ratios. However, the weight ratios of theactive compounds in the active compound combinations can be variedwithin a relatively wide range. In general,

[0308] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (1),

[0309] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (2),

[0310] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (3),

[0311] from 0.1 to 10 parts by weight, preferably from 0.2 to 5 parts byweight, of active compound of group (4),

[0312] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (5),

[0313] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (6),

[0314] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (7),

[0315] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (8),

[0316] from 0.02 to 50 parts by weight, preferably from 0.1 to 10 partsby weight, of active compound of group (9),

[0317] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (10),

[0318] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (11),

[0319] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (12),

[0320] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (13),

[0321] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (14),

[0322] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (15),

[0323] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (16),

[0324] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (17),

[0325] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (18),

[0326] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (19),

[0327] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (20),

[0328] from 0.05 to 20 parts by weight, preferably from 0.1 to 10 partsby weight, of active compound of group (21),

[0329] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (22),

[0330] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (23),

[0331] from 0.2 to 50 parts by weight, preferably from 0.04 to 10 partsby weight, of active compound of group (24),

[0332] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (25),

[0333] from 0.05 to 50 parts by weight, preferably from 0.1 to 20 partsby weight, of active compound of group (26),

[0334] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (27),

[0335] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (28),

[0336] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (29),

[0337] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (30),

[0338] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (31),

[0339] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (32),

[0340] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (33),

[0341] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (34),

[0342] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (35),

[0343] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (36),

[0344] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (37),

[0345] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (38),

[0346] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (39),

[0347] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (40),

[0348] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (41),

[0349] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (42),

[0350] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (43),

[0351] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (44),

[0352] from 0.1 to 150 parts by weight, preferably from 1 to 100 partsby weight, of active compound of group (45),

[0353] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (46),

[0354] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47a),

[0355] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47b),

[0356] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47c),

[0357] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47d),

[0358] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47e),

[0359] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47f),

[0360] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47 g),

[0361] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47 h),

[0362] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (47i),

[0363] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (48),

[0364] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (49),

[0365] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (50),

[0366] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (51),

[0367] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (52),

[0368] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (53),

[0369] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (54),

[0370] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (55),

[0371] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (56),

[0372] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (57),

[0373] from 0.1 to 50 parts by weight, preferably from 0.2 to 20 partsby weight, of active compound of group (58)

[0374] are present per part by weight of active compound of the formula(I).

[0375] The active compound combinations according to the invention havevery good fungicidal properties and can be employed for controllingphytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes,Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes,Deuteromycetes, etc.

[0376] The active compound combinations according to the invention areparticularly suitable for controlling Phytophthora infestans andPlasmopara viticola.

[0377] The fact that the active compound combinations are well toleratedby plants at the concentrations required for controlling plant diseasespermits the treatment of above-ground parts of plants, of propagationstock and seeds, and of the soil. The active compound combinationsaccording to the invention can be used for foliar application or else asseed dressing.

[0378] The active compound combinations according to the invention mayalso be employed to increase the yield of crops. Moreover, they havereduced toxicity and are tolerated well by plants.

[0379] All plants and plant parts can be treated in accordance with theinvention. Plants are to be understood as meaning in the present contextall plants and plant populations such as desired and undesired wildplants or crop plants (inclusive of naturally occurring crop plants).Crop plants can be plants which can be obtained by conventional plantbreeding and optimization methods or by biotechnological and recombinantmethods or by combinations of these methods, inclusive of the transgenicplants and inclusive of the plant varieties protectable or notprotectable by plant breeders' rights, such as shoot, leaf, flower androot, examples which may be mentioned being leaves, needles, stalks,stems, flowers, fruit bodies, fruits, seeds, roots, tubers and rhizomes.The plant parts also include harvested material, and vegetative andgenerative propagation material, for example cuttings, tubers, rhizomes,offsets and seeds.

[0380] As already mentioned above, it is possible to treat all plantsand their parts according to the invention. In a preferred embodiment,wild plant species and plant varieties, or those obtained byconventional biological breeding, such as crossing or protoplast fusion,and parts thereof, are treated. In a further preferred embodiment,transgenic plants and plant varieties obtained by genetical engineering,if appropriate in combination with conventional methods (GeneticModified Organisms), and parts thereof are treated. The term “parts” or“parts of plants” or “plant parts” has been explained above.

[0381] Particularly preferably, plants of the plant varieties which arein each case commercially available or in use are treated according tothe invention. Plant varieties are understood as meaning plants havingcertain properties (traits) that may be obtained by conventionalbreeding, by mutagenesis or by recombinant DNA techniques. These may bevarieties, bio- or genotypes.

[0382] Depending on the plant species or plant varieties, their locationand growth conditions (soils, climate, vegetation period, diet), thetreatment according to the invention may also result in superadditive(“synergistic”) effects. Thus, for example, reduced application ratesand/or a widening of the activity spectrum and/or an increase in theactivity of the substances and compositions to be used according to theinvention, better plant growth, increased tolerance to high or lowtemperatures, increased tolerance to draught or to water or soil saltcontent, increased flowering performance, easier harvesting, acceleratedmaturation, higher harvest yields, better quality and/or a highernutritional value of the harvested products, better storage stabilityand/or processability of the harvested products are possible whichexceed the effects which were actually to be expected.

[0383] The transgenic plants or plant varieties (i.e. those obtained bygenetical engineering) which are preferred and are to be treatedaccording to the invention include all plants which, in the geneticmodification, received genetic material which imparted particularlyadvantageous useful properties (“traits”) to these plants. Examples ofsuch properties are better plant growth, increased tolerance to high orlow temperatures, increased tolerance to drought or to water or soilsalt content, increased flowering performance, easier harvesting,accelerated maturation, higher harvest yields, better quality and/or ahigher nutritional value of the harvested products, better storagestability and/or processability of the harvested products. Further andparticularly emphasized examples of such properties are a better defenceof the plants against animal and microbial pests, such as againstinsects, mites, phytopathogenic fungi, bacteria and/or viruses, and alsoincreased tolerance of the plants to certain herbicidally activecompounds. Examples of transgenic plants which may be mentioned are theimportant crop plants, such as cereals (wheat, rice), maize, soya beans,potatoes, cotton, oilseed rape and also fruit plants (with the fruitsapples, pears, citrus fruits and grapevines), and particular emphasis isgiven to maize, soya beans, potatoes, cotton and oilseed rape. Traitsthat are emphasized are in particular increased defence of the plantsagainst insects by toxins formed in the plants, in particular thoseformed by the genetic material from Bacillus thuringiensis (for exampleby the genes CryIA(a), CryIA(b), CryIA(c), CryIIA, CryIIIA, CryIIIB2,Cry9c Cry2Ab, Cry3Bb and CryIF and also combinations thereof)(hereinbelow referred to as “Bt plants”). Traits that are alsoparticularly emphasized are the increased defence of the plants againstfungi, bacteria and viruses by Systematic Acquired Resistance (SAR),systemine, phytoalexines, elicitors and resistance genes andcorrespondingly expressed proteins and toxins. Traits that arefurthermore particularly emphasized are the increased tolerance of theplants to certain herbicidally active compounds, for exampleimidazolinones, sulphonylureas, glyphosate or phosphinotricin (forexample the “PAT” gene). The genes which impart the desired traits inquestion can also be present in combination with one another in thetransgenic plants. Examples of “Bt plants” which may be mentioned aremaize varieties, cotton varieties, soya bean varieties and potatovarieties which are sold under the trade names YIELD GARD® (for examplemaize, cotton, soya beans), KnockOut® (for example maize), StarLink®(for example maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf®(potato). Examples of herbicide-tolerant plants which may be mentionedare maize varieties, cotton varieties and soya bean varieties which aresold under the trade names Roundup Ready® (tolerance to glyphosate, forexample maize, cotton, soya bean), Liberty Link® (tolerance tophosphinotricin, for example oilseed rape), IMI® (tolerance toimidazolinones) and STS® (tolerance to sulphonylureas, for examplemaize). Herbicide-resistant plants (plants bred in a conventional mannerfor herbicide tolerance) which may be mentioned include the varietiessold under the name Clearfield® (for example maize). Of course, thesestatements also apply to plant varieties having these or still to bedeveloped genetic traits, which plants will be developed and/or marketedin the future.

[0384] The plants listed can be treated according to the invention in aparticularly advantageous manner with the compounds of the generalformula I or the active compound mixtures according to the invention.The preferred ranges stated above for the active compounds or mixturesalso apply to the treatment of these plants. Particular emphasis isgiven to the treatment of plants with the compounds or mixturesspecifically mentioned in the present text.

[0385] The treatment of the plants and parts of plants according to theinvention with the active compounds is carried out directly or by actionon their environment, habitat or storage area according to customarytreatment methods, for example by dipping, spraying, evaporating,atomizing, broadcasting, brushing-on and, in the case of propagationmaterial, in particular in the case of seeds, furthermore by one- ormulti-layer coating.

[0386] The active compound combinations according to the invention canbe converted to the customary formulations, such as solutions,emulsions, suspensions, powders, foams, pastes, granules, aerosols andmicroencapsulations in polymeric substances and in coating compositionsfor seeds, and ULV formulations.

[0387] These formulations are produced in a known manner, for example bymixing the active compounds or active compound combinations withextenders, that is liquid solvents, liquefied gases under pressure,and/or solid carriers, optionally with the use of surfactants, that isemulsifiers and/or dispersants, and/or foam formers. If the extenderused is water, it is also possible to use, for example, organic solventsas auxiliary solvents. Essentially, suitable liquid solvents include:aromatics such as xylene, toluene or alkylnaphthalenes, chlorinatedaromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes,chloroethylenes or methylene chloride, aliphatic hydrocarbons such ascyclohexane or paraffins, for example petroleum fractions, alcohols suchas butanol or glycol and their ethers and esters, ketones such asacetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone,strongly polar solvents such as dimethylformamide and dimethylsulphoxide, or else water.

[0388] Liquefied gaseous extenders or carriers are to be understood asmeaning liquids which are gaseous at ambient temperature and underatmospheric pressure, for example aerosol propellants such as butane,propane, nitrogen and carbon dioxide. Suitable solid carriers are: forexample ground natural minerals such as kaolins, clays, talc, chalk,quartz, attapulgite, montmorillonite or diatomaceous earth, and groundsynthetic minerals such as finely divided silica, alumina and silicates.Suitable solid carriers for granules are: for example crushed andfractionated natural rocks such as calcite, marble, pumice, sepioliteand dolomite, or else synthetic granules of inorganic and organic meals,and granules of organic material such as sawdust, coconut shells, maizecobs and tobacco stalks. Suitable emulsifiers and/or foam formers are:for example nonionic and anionic emulsifiers, such as polyoxyethylenefatty acid esters, polyoxyethylene fatty alcohol ethers, for examplealkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates,arylsulphonates, or else protein hydrolysates. Suitable dispersants are:for example lignin-sulphite waste liquors and methylcellulose.

[0389] Tackifiers such as carboxymethylcellulose and natural andsynthetic polymers in the form of powders, granules or latices, such asgum arabic, polyvinyl alcohol and polyvinyl acetate, or else naturalphospholipids such as cephalins and lecithins and syntheticphospholipids can be used in the formulations. Other additives can bemineral and vegetable oils.

[0390] It is possible to use colorants such as inorganic pigments, forexample iron oxide, titanium oxide and Prussian Blue, and organicdyestuffs such as alizarin dyestuffs, azo dyestuffs and metalphthalocyanine dyestuffs, and trace nutrients such as salts of iron,manganese, boron, copper, cobalt, molybdenum and zinc.

[0391] The formulations generally comprise between 0.1 and 95% by weightof active compounds, preferably between 0.5 and 90%.

[0392] The active compound combinations according to the invention, assuch or in their formulations, can also be applied in a mixture withknown fungicides, bactericides, acaricides, nematicides or insecticides,to broaden the activity spectrum or to prevent the development ofresistance, for example. In many cases, synergistic effects areobtained, i.e. the activity of the mixture is greater than the activityof the individual components.

[0393] A mixture with other known active compounds such as herbicides orwith fertilizers and growth regulators is also possible.

[0394] The active compound combinations can be used as such, in the formof their formulations or as the use forms prepared therefrom, such asready-to-use solutions, emulsifiable concentrates, emulsions,suspensions, wettable powders, soluble powders and granules. They areused in the customary manner, for example by watering, spraying,atomizing, scattering, spreading, and as a powder for dry seedtreatment, a solution for seed treatment, a water-soluble powder forseed treatment, a water-soluble powder for slurry treatment, or byencrusting.

[0395] When using the active compound combinations according to theinvention, the application rates can be varied within a relatively widerange, depending on the kind of application. In the treatment of partsof plants, the application rates of the active compound combination aregenerally between 0.1 and 10,000 g/ha, preferably between 10 and 1000g/ha. In the treatment of seeds, the application rates of the activecompound combination are generally between 0.001 and 50 g per kilogramof seed, preferably between 0.01 and 10 g per kilogram of seed. In thetreatment of the soil, the application rates of the active compoundcombination are generally between 0.1 and 10,000 g/ha, preferablybetween 1 and 5000 g/ha.

[0396] The good fungicidal activity of the active compound combinationsaccording to the invention is evident from the examples below. While theindividual active compounds exhibit weaknesses with regard to thefungicidal activity, the combinations have an activity which exceeds thesum of individual activities.

[0397] A synergistic effect of fungicides is always present when thefungicidal activity of the active compound combinations exceeds thetotal of the activities of the active compounds when appliedindividually.

[0398] The expected activity for a given combination of two activecompounds can be calculated as follows (cf. Colby, S. R., “CalculatingSynergistic and Antagonistic Responses of Herbicide Combinations”, Weeds15, (1967), 20-22):

[0399] If

[0400] X is the efficacy when applying active compound A at anapplication rate of m g/ha,

[0401] Y is the efficacy when applying active compound B at anapplication rate of n g/ha and

[0402] E is the efficacy when applying the active compounds A and B atan application rate of m and n g/ha,

[0403] then $E = {X + Y - \frac{X \cdot Y}{100}}$

[0404] The efficacy is calculated in %. 0% is an efficacy whichcorresponds to that of the control, whereas an efficacy of 100% meansthat no infection is observed.

[0405] If the actual fungicidal activity exceeds the calculated value,then the activity of the combination is superadditive, i.e. asynergistic effect exists. In this case, the efficacy which was actuallyobserved must be greater than the value for the expected efficacy (E)calculated from the abovementioned formula.

[0406] The example that follows illustrates the invention. However, theinvention is not limited to the example.

EXAMPLE

[0407] Plasmopara Test (Grapevine)/Protective

[0408] Solvent: 49 parts by weight of acetone

[0409] Emulsifier: 1 part by weight of alkyl-aryl polyglycol ether

[0410] To produce a suitable preparation of active compound, 1 part byweight of active compound or active compound combination is mixed withthe stated amounts of solvent and emulsifier, and the concentrate isdiluted with water to the desired concentration, or a commerciallyavailable formulation of active compound or active compound combinationis diluted with water to the desired concentration.

[0411] To test for protective activity, young plants are sprayed withthe preparation of active compound at the stated application rate. Afterthe spray coating has dried on, the plants are inoculated with anaqueous spore suspension of Plasmopara viticola and then remain in anincubation cabin at approximately 20° C. and 100% relative atmospherichumidity for 1 day. The plants are then placed in a greenhouse atapproximately 21° C. and approximately 90% atmospheric humidity for 4days. The plants are then moistened and then placed in an incubationcabin for 1 day.

[0412] Evaluation is carried out 6 days after the inoculation. 0% meansan efficacy which corresponds to that of the control, whereas anefficacy of 100% means that no infection is observed.

[0413] The expected activity for a given combination of two activecompounds can be calculated as follows (cf. Colby, S. R., “CalculatingSynergistic and Antagonistic Responses of Herbicide Combinations”, Weeds15, (1967), 20-22);

[0414] If

[0415] X is the efficacy when applying active compound A at anapplication rate of m g/ha,

[0416] Y is the efficacy when applying active compound B at anapplication rate of n g/ha and

[0417] E is the efficacy when applying the active compounds A and B atan application rate of m and n g/ha,

[0418] then $E = {X + Y - \frac{X \cdot Y}{100}}$

[0419] The efficacy is calculated in %. 0% is an efficacy whichcorresponds to that of the control, whereas an efficacy of 100% meansthat no infection is observed.

[0420] If the actual fungicidal activity exceeds the calculated value,then the activity of the combination is superadditive, i.e. asynergistic effect exists. In this case, the efficacy which was actuallyobserved must be greater than the value for the expected efficacy (E)calculated from the abovementioned formula.

[0421] The table below shows clearly that the efficacy observed for theactive compound combination according to the invention is greater thanthe efficacy that was calculated, i.e. a synergistic effect exists.TABLE Plasmopara test (grapevine)/protective Active compound applicationrate in Active compound g/ha % efficacy Known: Ib 10 66

Copper oxychloride (XXXXVIa) 100 26 Active Expected compound efficacy,application Actual calculated using Mixing ratio rate in g/ha efficacyColby's formula Mixture according to the invention: (Ib) + 10 + 75Copper oxychlonde {close oversize brace} 1:10 {close oversize brace} 89(XXXXVIa) 100

1. Active compound combinations, comprising at least one compound of the general formula (I),

in which R¹ represents unsubstituted or fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, 1- or t-butyl-, methoxy-, ethoxy- or phenoxy-substituted phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl, indanyl, 2-benzofuranyl, 2-benzothienyl, 2-thienyl or 2-furanyl, and (1) a triazole derivative of the formula

in which X represents chlorine or phenyl and Y represents

and/or (2) the triazole derivative of the formula

and/or (3) an aniline derivative of the formula

in which R¹ represents hydrogen or methyl, and/or (4) N-[1-(4-chloro-phenyl)-ethyl]-2,2-dichloro-1-ethyl-3-methyl-cyclopropane-carboxamide of the formula

and/or (5) the zinc propylene-1,2-bis-(dithiocarbamidate) of the formula

and/or (6) at least one thiocarbamate of the formula

Me=Zn or Mn or a mixture of Zn and Mn and/or (7) the aniline derivative of the formula

and/or (8) the compound of the formula

and/or (9) the benzothiadiazole derivative of the formula

and/or (10) the 8-t-butyl-2-(N-ethyl-N-n-propyl-amino)-methyl-1,4-dioxa-spiro[5,4]-decane of the formula

and/or (11) the compound of the formula

and/or (12) the compound of the formula

and/or (13) the compound of the formula

and/or (14) the cyanoxime derivative of the formula

and/or (15) a pyrimidine derivative of the formula

in which R² represents methyl or cyclopropyl, and/or (16) an aniline derivative of the formula

and/or (17) the morpholine derivative of the formula

and/or (18) the phthalimide derivative of the formula

and/or (19) the phosphorus compound of the formula

and/or (20) the hydroxyethyl-triazole derivative of the formula

and/or (21) the 1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimine of the formula

and/or (22) the oxazolidinedione of the formula

and/or (23) the benzamide derivative of the formula

and/or (24) a guanidine derivative of the formula

in which m represents integers from 0 to 5 and R³ represents hydrogen (17 to 23%) or the radical of the formula

and/or (25) the triazole derivative of the formula

and/or (26) the halogeno-benzimidazole of the formula

and/or (27) the halogenopyrimidine of the formula

and/or (28) the tetrachloro-isophthalo-dinitrile of the formula

and/or (29) the compound of the formula

and/or (30) the pyridinamine of the formula

and/or (31) the thiazolecarboxamide of the formula

and/or (32) the sulphonamide of the formula

and/or (33) the compound of the formula

and/or (34) the compound of the formula

and/or (35) the compound of the formula

and/or (36) the diamide of the formula

and/or (37) the methoxyacrylate derivative of the formula

and/or (38) the quinoline derivative of the formula

and/or (39) the phenylamide derivative of the formula

and/or (40) the phenylamide derivative of the formula

and/or (41) the dicarboxime derivative of the formula

and/or (42) the phosphonic acid of the formula

and/or (43) the pyrrole derivative of the formula

and/or (44) the phenyl carbonate of the formula

and/or (45) a) copper oxychloride  (XXXXVIa) b) copper hydroxide  (XXXXVIb) and/or (46) the imidazole derivative of the formula

and/or (47) a triazole derivative of the formula

and/or (48) the compound of the formula

and/or (49) N-methyl-2-(methoxyimino)-2-[2-([1-(3-tri-fluoro-methyl-phenyl)ethoxy]iminomethyl)phenyl]acetamide of the formula

and/or (50) 2-[2-([2-phenyl-2-methoxyimino-1-methylethyl]-imino-oxymethyl)phenyl]-2-methoxyimino-N-methylacetamide of the formula

and/or (51) 2-[2-([2-(4-fluorophenyl)-2-methoxyimino-1-methylethyl]imino-oxymethyl)phenyl]-2-methoxyimino-N-methyl-acetamide of the formula

and/or (52) 2-[4-methoxy-3-(1-methylethoxy)-1,4-diazabuta-1,3-dienyl-oxymethyl]phenyl-2-methoximino-N-methyl-acetamide of the formula

and/or (53) methyl N-(2-[1-(4-chlorophenyl)pyrazol-3-yloxymethyl]phenyl)-N-methoxycarbamate of the formula

and/or (54) 2,4-dihydro-5-methoxy-2-methyl-4-[2-([([1-(3-tri-fluoromethyl-phenyl)ethylidene] amino)oxy] methyl)phenyl]-3H-1,2,4-triazol-3-one of the formula

and/or (55) the compound of the formula

and/or (56) the compound of the formula

and/or (57) a compound of the formula

in which R¹ represents fluorine (XXXXXVIIIa) or chlorine (XXXXXVIIIb), and/or (58) the compound of the formula


2. Fungicidal mixtures according to claim 1, comprising compounds of the formula (I) in which R¹ represents unsubstituted or fluorine-, chlorine-, bromine-, methyl- or ethyl-substituted phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl.
 3. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (Ia)


4. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (Ib)


5. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (Ic)


6. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (Id)


7. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (Ie)


8. Fungicidal mixtures according to claim 1, comprising as compounds of the formula (I) compounds of the formula (If)


9. Composition according to at least one of claims 1 to 8, characterized in that in the active compound combinations the weight ratio of active compound of active compound of the formula (I) to active compound of group (1) is from 1:0.1 to 1:50, active compound of group (2) is from 1:0.1 to 1:50, active compound of group (3) is from 1:1 to 1:150, active compound of group (4) is from 1:0.1 to 1:10, active compound of group (5) is from 1:1 to 1:150, active compound of group (6) is from 1:1 to 1:150, active compound of group (7) is from 1:0.1 to 1:50, active compound of group (8) is from 1:0.1 to 1:50, active compound of group (9) is from 1:0.02 to 1:50, active compound of group (10) is from 1:0.1 to 1:50, active compound of group (11) is from 1:0.1 to 1:50, active compound of group (12) is from 1:0.1 to 1:50, active compound of group (13) is from 1:0.1 to 1:50, active compound of group (14) is from 1:0.1 to 1:50, active compound of group (15) is from 1:0.1 to 1:50, active compound of group (16) is from 1:0.1 to 1:50, active compound of group (17) is from 1:0.1 to 1:50, active compound of group (18) is from 1:0.1 to 1:150, active compound of group (19) is from 1:0.1 to 1:150, active compound of group (20) is from 1:0.1 to 1:50, active compound of group (21) is from 1:0.05 to 1:20, active compound of group (22) is from 1:0.1 to 1:50, active compound of group (23) is from 1:0.1 to 1:50, active compound of group (24) is from 1:0.02 to 1:50, active compound of group (25) is from 1:0.1 to 1:50, active compound of group (26) is from 1:0.05 to 1:50, active compound of group (27) is from 1:0.1 to 1:50, active compound of group (28) is from 1:0.1 to 1:150, active compound of group (29) is from 1:1 to 1:150, active compound of group (30) is from 1:0.1 to 1:50, active compound of group (31) is from 1:0.1 to 1:50, active compound of group (32) is from 1:0.1 to 1:50, active compound of group (33) is from 1:0.1 to 1:50, active compound of group (34) is from 1:0.1 to 1:50, active compound of group (35) is from 1:0.1 to 1:50, active compound of group (36) is from 1:0.1 to 1:150, active compound of group (37) is from 1:0.1 to 1:50, active compound of group (38) is from 1:0.1 to 1:50, active compound of group (39) is from 1:0.1 to 1:50, active compound of group (40) is from 1:0.1 to 1:50, active compound of group (41) is from 1:0.1 to 1:150, active compound of group (42) is from 1:0.1 to 1:150, active compound of group (43) is from 1:0.1 to 1:50, active compound of group (44) is from 1:0.1 to 1:50, active compound of group (45) is from 1:0.1 to 1:150, active compound of group (46) is from 1:0.1 to 1:50, active compound of group (47a) is from 1:0.1 to 1:50, active compound of group (47b) is from 1:0.1 to 1:50, active compound of group (47c) is from 1:0.1 to 1:50, active compound of group (47d) is from 1:0.1 to 1:50, active compound of group (47e) is from 1:0.1 to 1:50, active compound of group (47f) is from 1:0.1 to 1:50, active compound of group (47 g) is from 1:0.1 to 1:50, active compound of group (47 h) is from 1:0.1 to 1:50, active compound of group (47i) is from 1:0.1 to 1:50, active compound of group (48) is from 1:0.1 to 1:50, active compound of group (49) is from 1:0.1 to 1:50, active compound of group (50) is from 1:0.1 to 1:50, active compound of group (51) is from 1:0.1 to 1:50, active compound of group (52) is from 1:0.1 to 1:50, active compound of group (53) is from 1:0.1 to 1:50, active compound of group (54) is from 1:0.1 to 1:50, active compound of group (55) is from 1:0.1 to 1:50, active compound of group (56) is from 1:0.1 to 1:50, active compound of group (57) is from 1:0.1 to 1:50, active compound of group (58) is from 1:0.1 to 1:50.
 10. Method for controlling fungi, characterized in that the active compound combinations according to at least one of claims 1 to 9 are applied to the fungi and/or their habitat.
 11. Use of active compound combinations according to at least one of claims 1 to 9 for controlling fungi.
 12. Process for preparing fungicidal compositions, characterized in that active compound combinations according to at least one of claims 1 to 9 are mixed with extenders and/or surfactants. 